Characterization of a Dialdehyde Chitosan Generated by Periodate Oxidation

Authors

  • I. CHARHOUF
  • A. BENNAMARA
  • A. ABOURRICHE
  • A. CHENITE
  • J. ZHU
  • M. BERRADA

Keywords:

Periodate, Selective oxidation, Chitosan, Dialdehydes

Abstract

This article reports the oxidation of Chitosan by using periodate and the characterization of the dialdehyde chitosan (DAC) generated by the reaction. Oxidised chitosan were further characterised by FTIR analysis, 1HNMR and TGA. The morphological analyses of oxidized chitosan by SEM confirmed the non change of elongated and fibrous network of chitosan. FTIR and TGA show no significant change on chemical structure and thermal properties successively. 1H NMR study confirmed the presence of imines generated by the reaction between dialdehyde chitosan and amino groups of chitosan (spontaneous assembling).

Author Biography

M. BERRADA

Hassan II University of CasablancaFaculty of Sciences Ben M'SikCasablanca, Morocco

References

Athanasios G. Vlessidis and Nicholaos P. Evmiridis, Periodate oxidation and its contribution to instrumental methods of micro-analysis

Jiugao Yu, Peter R. Chang, Xiaofei Ma, The preparation and properties of dialdehyde starch and thermoplastic dialdehyde starch, Carbohydrate Polymers 79 (2010) 296

D. A. White, D. S. Miyada, and R. M. Nakamura, Characterization of the periodate oxidation of glycerol and related Compounds and Application toward determination of Serum Triglyceride concentrations, CLIN.CHEM. (1974) 20/6, 645-648.

Chandroth Kalyad Simi, Tholath Emilia Abraham, Transparent xyloglucan

Wen-Yu Su, Yu-Chun Chen, Feng-Huei Lin, Injectable oxidized hyaluronic acid/adipic acid dihydrazide hydrogel for nucleus pulposus regeneration, Acta Biomaterialia 6 (2010) 3044

Inger M. N. Vold and Bj

K

Bj

V.K. Mourya, Nazma N. Inamdar, Chitosan-modifications and applications: Opportunities galore, Reactive & Functional Polymers 68 (2008) 1013

Huiying Luo, Juan Li, Xuan Chen, Antitumor effect of N-succinyl-chitosan nanoparticles on K562 cells, Biomedicine & Pharmacotherapy 64 (2010) 521

Jung Kwon Oh, Ray Drumright, Daniel J. Siegwart, Krzysztof Matyjaszewski, The development of microgels/nanogels for drug delivery applications, Prog. Polym. Sci. 33 (2008) 448

Paul Baldrick, The safety of chitosan as a pharmaceutical excipient, Regulatory Toxicology and Pharmacology 56 (2010) 290

Riccardo A.A. Muzzarelli, Genipin-crosslinked chitosan hydrogels as biomedical and pharmaceutical aids, Carbohydrate Polymers 77 (2009) 1

V.R. Sinha, A.K. Singla, S. Wadhawan, R. Kaushik, R. Kumria, K. Bansal, S. Dhawan, Chitosan microspheres as a potential carrier for drugs, International Journal of Pharmaceutics 274 (2004) 1

Kyoko Kofuji, Chun-Jun Qian, Masumi Nishimura, Ikumi Sugiyama, Yoshifumi Murata, Susumu Kawashima, Relationship between physicochemical characteristics and functional properties of chitosan, European Polymer Journal 41 (2005) 2784

Yan Feng, Limin Yang and Feng Li, A novel sensing platform based on periodate-oxidized chitosan, Anal. Methods (2010), 2, 2011

Vincenza Ferraro, Isabel B. Cruz, Ruben Ferreira Jorge, F. Xavier Malcata, Manuela E. Pintado, Paula M.L. Castro, Valorisation of natural extracts from marine source focused on marine by-products: A review, Food Research International (2010).

Paula C.A. Jer

Zouhour Limam, Salah Selmi, Saloua Sadok and Amor El Abed, Extraction and characterization of chitin and chitosan from crustacean by-products: Biological and physicochemical properties, African Journal of Biotechnology (2011) Vol. 10 (4), pp. 640-647.

Gr

Chendur Palpandi, Vairamani Shanmugam and Annaian Shanmugam, Extraction of chitin and chitosan from shell and operculum of mangrove gastropod Nerita (Dostia) crepidularia Lamarck, International Journal of Medicine and Medical Sciences (2009) Vol 1(5) pp.198-205.

Sanchita Sharmin Chowdhury, Md. Al-Amin, Mariam Jamila, Samiul Haque, Taksim Ahmed and Mohammed Ehsanul Hoque Mazumder, Infrared spectroscopic characterization, free radical scavenging and cytotoxic evaluation of chitosan extracted from Penaeus monodon shells (2009) S. J. Pharm. Sci. 2(2): 27-30.

Marguerite Rinaudo, Chitin and chitosan: Properties and applications, Prog. Polym. Sci. 31 (2006) 603

Inmaculada Aranaz, Marian Meng

Giovanna Gomez d

Riccardo A.A. Muzzarelli, Chitins and chitosans for the repair of wounded skin, nerve, cartilage and bone, Carbohydrate Polymers 76 (2009) 167

Niu Mei, Liu Xuguang, Dai Jinming, Jia Husheng, Wei Liqiao, Xu Bingshe, Antibacterial activity of chitosan coated Ag-loaded nano-SiO2 composites, Carbohydrate Polymers 78 (2009) 54

Inger M. N. Vold and Bj

K

Mohammad R. Kasaai, A review of several reported procedures to determine the degree of N-acetylation for chitin and chitosan using infrared spectroscopy, Carbohydrate Polymers 71 (2008) 497

Guobiao Chu and Chunbao Li, Convenient and Clean Synthesis of Imines from Primary Benzylamines, the Royal Society of Chemistry (2010).

Downloads

Published

2014-11-12

How to Cite

CHARHOUF, I., BENNAMARA, A., ABOURRICHE, A., CHENITE, A., ZHU, J., & BERRADA, M. (2014). Characterization of a Dialdehyde Chitosan Generated by Periodate Oxidation. International Journal of Sciences: Basic and Applied Research (IJSBAR), 16(2), 336–348. Retrieved from https://gssrr.org/index.php/JournalOfBasicAndApplied/article/view/3035

Issue

Vol. 16 No. 2 (2014)

Section

Articles

License

Authors who submit papers with this journal agree to the following terms.