Leaching of Lanthanides from Phosphogypsum Waste using Nonyl Phenol Ethoxylate Associated with HNO3 and HCl

Authors

  • Mohamed Nouh Kouraim Nuclear Materials Authority
  • Mohamed Mohamed Fawzy Nuclear Materials Authority
  • Osama Saad Helaly Nuclear Materials Authority

Keywords:

Leaching, Lanthanides, Phosphogypsum Waste, Nitric Acid, Hydrochloric Acid, Nonyl Phenol Ethoxylate

Abstract

Leaching of lanthanides from phosphogypsum (PG) was carried out using either free acids such as HCl and HNO3 or these acids associated with Nonyl Phenol Ethoxylate (NPE). The factors affecting the leaching process were optimized. Also the kinetics of the leaching investigated as a function of temperature. Based on the experimental results NPE increased the leaching efficiency by 30 % relative to the corresponding free acids. It was found that the leaching process could be described by a shrinking-core model. Also the leaching of lanthanides by the associated system decrease the activation energy from

References

. E. P. Lokshin, , Y. A. Vershkova, A. V. Vershkov, O. A. Tareeva, "Efficiency of sulfuric acid leaching of lanthanides in relation to quality of phospho-semihydrate obtained from khibiny apatite concentrate." Russian J. App. Chem., vol. 75, pp. 1572-1576, 2002.

. F. Henry and B. Stephen,

. M.A. Eid, J.A. Broekaert, and P.A. Tschopel,

. M. A. Eid, A. A. Fakhry, A. A. Mahdy, K. A. Eid and J. A. Broekaert,

. F. Hassan, and, A. El-Kammar,

. H.Tayibi, M.Choura, F.Lopez, F.Alguacil, and A. Delgado,

. F. Habashi,

. H. El-Didamony, M.M. Ali, N.S. Awwad, M.M. Fawzy, and M.F. Attallah,

. J. Arocena, P. Rutherford, and M. Dudas,

. E. P. Lokshin, , Y. A. Vershkova, A. V. Vershkov, O. A. Tareeva,

. A. M. Andrianov, N.F. Rusin, L.M. Burtnenko, B.D. Fedorenko, and M. K. Olmezov,

. A. M. Andrianov, N. F. Rusin, G. F. Dejneka, T. A. Zinchenko, and T. I. Burova,

. D. A. Clur, and K. R. Hasen,

. Z. I. Zafar and M. Ashraf,

. R. Chi, J. Tian, G. Zhu, Y. Wu, S. Li, C. Wang, and Z. A, Zhou,

. M. M. Ali, N.A. Mohammed,

. A. T. Kandil, M. M. Aly, E. M. Moussa, A. M. Kamel, M. M. Gouda, M.N. Kouraim,

. Z. Marczenko. Spectrophotometric Determination of Elements. New York, John Wiley and Sons, Inc., 1986.

. G.M. Klecka, C.A. Staples, C.G. Naylor, and B.S. Losey,

. O. Ya. Neiland. Organic Chemistry. Moscow, Vysshaya Shkola, 1990.

. C. J. B. Mott. Anion and Ligand Exchange. In the Chemistry of Soil Processes. Chichester, John Wiley and Sons, 1981.

Downloads

Published

2014-06-24

How to Cite

Kouraim, M. N., Fawzy, M. M., & Helaly, O. S. (2014). Leaching of Lanthanides from Phosphogypsum Waste using Nonyl Phenol Ethoxylate Associated with HNO3 and HCl. International Journal of Sciences: Basic and Applied Research (IJSBAR), 16(2), 31–44. Retrieved from https://gssrr.org/index.php/JournalOfBasicAndApplied/article/view/2065

Issue

Section

Articles