Adhesive Compositions based on Heptene-1 Copolymer with Maleic Anhydride

Authors

  • F. A. Amirov Azerbaijan State University of Oil and Industry
  • R.E. Mammadova Azerbaijan State University of Oil and Industry
  • N. A. Guliyeva Azerbaijan State University of Oil and Industry

Keywords:

heptene-1, maleic anhydride, copolymer, epoxy resin, adhesive composition, degree of swelling, tensile strength, dielectric constant

Abstract

Adhesive compositions based on hepten-1-maleic anhydride co-polymer and ED-16 epoxide resin were prepared and some physical and physico-chemical properties of these adhesive compositions were determined. The ability of the prepared adhesive composition to bond aluminum and steel plates was also studied. Adhesive compositions of hepten-1-maleic anhydride copolymer and ED-16 epoxy resin in different ratios (10, 15, 20, 25, 30 s.c. copolymer to 100 s.c. ED-20 epoxide resin) were prepared. Curing of ED-16 epoxy resin with co-polymer (CP) was studied and the effect of temperature and amount of co-polymer on curing was determined. The adhesive properties of aluminum and steel plates were studied

Adhesive compositions based on hepten-1-maleic anhydride co-polymer and ED-16 epoxide resin were prepared and some physical and physico-chemical properties of these adhesive compositions were determined. The ability of the prepared adhesive composition to bond aluminum and steel plates was also studied. Adhesive compositions of hepten-1-maleic anhydride copolymer and ED-16 epoxy resin in different ratios (10, 15, 20, 25, 30 s.c. copolymer to 100 s.c. ED-20 epoxide resin) were prepared. Curing of ED-16 epoxy resin with co-polymer (CP) was studied and the effect of temperature and amount of co-polymer on curing was determined. The adhesive properties of aluminum and steel plates were studied by hardening under different conditions. It was determined that the strength of the adhesive compositions prepared in different mass ratios of joint polymer and ED-16 epoxy resin for aluminum plates with a ratio of ED-16:CP=100:25 to fracture resistance. was higher for When the adhesive composition with this composition is cured at 160, 180, 200 0 C for 3 hours, the strength against sliding breakage for duralumin plates were 24.8, 26.2 and 25.8 MPa. The tensile strength ¬and dielectric properties of the adhesive composition prepared in the ratio of ED-16:CP=100:25 were determined.

by hardening under different conditions. It was determined that the strength of the adhesive compositions prepared in different mass ratios of joint polymer and ED-16 epoxy resin for aluminum plates with a ratio of ED-16:CP=100:25 to fracture resistance. was higher for When the adhesive composition with this composition is cured at 160, 180, 200 0 C for 3 hours, the strength against sliding breakage for duralumin plates were 24.8, 26.2 and 25.8 MPa. The tensile strength ¬and dielectric properties of the adhesive composition prepared in the ratio of ED-16:CP=100:25 were determined.

References

. Chunfu Chen, Bin Li, Masao Kanari and Daoqiang Lu . Epoxy Adhesives. Chapter Metrics Overview . 2019

. Kablov, E.N., Chursova, L.V., Lukina, N.F. et al. A study of epoxide–polysulfone polymer systems for high-strength adhesives of aviation purpose. Polym. Sci. Ser. D 10, pp. 225–229 (2017). https://doi.org/10.1134/S1995421217030066.

. Kochergin, Y.S., Pyrikov, A.V., Kulik, T.A. et al. Investigation of epoxide adhesive compositions cured with polyoxypropylene triamine. Polym. Sci. Ser. D 3, pp. 47–49 (2010). https://doi.org/10.1134/S1995421210010077

. Petrova, A.P., Lukina, N.F., Dement’eva, L.A. et al. Film structural adhesives. Polym. Sci. Ser. D 8, pp. 138–143 (2015). https://doi.org/10.1134/S1995421215020148

. Fedoseev, M., Gurina, M., Sdobnov, V. and Kondyurin, A. (1996), Study of the Reaction of Epoxides with Carboxylic Acids by IR and Raman Spectrometry. J. Raman Spectrosc., 27: pp. 413-418. https://doi.org/10.1002/(SICI)1097-4555(199605)27:5<413::AID-JRS947>3.0.CO;2-T

. Vyatkina, M.A., Gorbatkina, Y.A., Gorbunova, I.Y. et al. Effect of Oligomeric Copolyimides on the Properties of Epoxy Binders. Mech Compos Mater 58, pp. 857–866 (2023). https://doi.org/10.1007/s11029-023-10074-1

. Konoplin, A.Y., Baurova, N.I. Thermogravimetric Analysis of a Weld-Bonded Joint with Various Types of Adhesive Materials. Polym. Sci. Ser. D 15, pp. 166–170 (2022). https://doi.org/10.1134/S1995421222020125

. Gur’eva, L.L., Kuzub, L.I., Tarasov, A.E. et al. Epoxy Nanocomposites Containing Silver Nanoparticles with Oligostyrylcarboxylate Ligands. Polym. Sci. Ser. B 64, pp. 209–218 (2022). https://doi.org/10.1134/S1560090422020105

. Sirotin, I.S., Son, V.X., Gorbunova, E.A. et al. The Composition and Some Properties of Epoxy Oligomers Based on Hexachlorocyclotriphosphazene and Diphenylolpropane. Polym. Sci. Ser. D 15, pp. 457–463 (2022). https://doi.org/10.1134/S1995421222030261

. G. Fantin et al., “Functionalization of poly(organophosphazenes)—III. Synthesis of phosphazene materials containing carbon-carbon double bonds and epoxide groups,” Eur. Polym. J. 29, pp. 1571–1579 (1993).

. J. Sun, X. Wang, and D. Wu, “Novel spirocyclic phosphazene-based epoxy resin for halogen-free fire resistance: synthesis, curing behaviors, and flammability characteristics,” ACS Appl. Mater. Interfaces 4, pp. 4047–4061 (2012).

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Published

2024-03-16

How to Cite

F. A. Amirov, R.E. Mammadova, & N. A. Guliyeva. (2024). Adhesive Compositions based on Heptene-1 Copolymer with Maleic Anhydride. International Journal of Sciences: Basic and Applied Research (IJSBAR), 72(1), 248–254. Retrieved from https://gssrr.org/index.php/JournalOfBasicAndApplied/article/view/16538

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