Mechanical and Antibacterial Properties of Polyester/Chitosan/Ag Nanocomposite

Authors

  • Md. Ashadul Islam Department of Materials Science and Engineering, University of Rajshahi, Rajshahi-6205, Bangladesh
  • Md. Waresh Hossain Department of Materials Science and Engineering, University of Rajshahi, Rajshahi-6205, Bangladesh
  • Sajib Madbar Department of Materials Science and Engineering, University of Rajshahi, Rajshahi-6205, Bangladesh
  • Md. Asadul Hoque Department of Materials Science and Engineering, University of Rajshahi, Rajshahi-6205, Bangladesh

Keywords:

Nanoparticles (Ag), Nanocomposite, Chitosan, Polyester resin, Antimicrobial

Abstract

This projects development of a new type of lightweight polymer-based nanocomposite material, utilizing polyester resin as the matrix and incorporating Ag nanoparticles and chitosan as filler materials. Polyester based composites products sometimes suffers from mechanical failure, weather adaption and microbial attack. Our findings demonstrate significant advancements in both mechanical and antibacterial properties of these nanocomposites. Chitosan and Silver (Ag) nanoparticles reinforced polyester based nanocomposites were prepared where chitosan were synthesized from shrimp shell and Ag nanoparticles were synthesized by chemical reduction method. Different percentage of (wt%) chitosan were loaded in polyester matrix and 2.5wt% chitosan loading was found to be optimized. In the optimized polyester-chitosan system different percentage (2.5, 5, 7.5) wt% of Ag nanoparticles were dispersed as reinforcement to fabricate polyester/chitosan/Ag nanocomposites. The resultant polyester based nanocomposites were (i) polyester/chitosan/2.5wt% Ag, (ii) polyester/chitosan/5wt% Ag, (iii) polyester/chitosan/7.5wt% Ag which were compared with the blank polyester resin sheet and optimized polyester/chitosan composite for the investigation of mechanical ( tensile strength, young’s modulus, flexural strength, flexural strain and hardness), water absorption and antimicrobial activities. Among the entire composite and nanocomposites the polyester/chitosan/2.5wt%Ag showed the best results in an average with respect to mechanical, water absorption and antimicrobial activities.

References

. E. Thostenson, C. Li, and T. Chou, “Review Nanocomposites in Context”, Journal of Composites Science & Technology, vol. 65, pp. 491-516, 2005.

. JE Hulla, SC Sahu and AW Hayes, “Nanotechnology: History and future. Hum Exp Toxicol”, vol. 34(12), pp. 1318-1321, 2015.

. D. Schmidt, D. Shah, and E.P. Giannelis, “New Advances in Polymer/Layered Silicate Nanocomposites”, Current Opinion in Solid State and Materials Science, vol. 6, pp. 205-212, 2002.

. D.R. Askeland, P.P. Fulay, and D.K. Bhattacharya, “Essentials of Materials Science and Engineering, CL Engineering, 3rd Edition, New York (2013).

. Rajashekar Reddy Palle, Jens Schuster, Yousuf Pasha Shaik, Monis Kazmi, “Fabrication and Characterization of Glass Fiber with SiC Reinforced Polymer Composites”, Open Journal of Composite Materials, vol. 12, pp. 16-29, 2022.

. Ayesha Kausar, “Review of fundamentals and applications of polyester nanocomposites filled with carbonaceous nanofillers, Journal of plastic film and sheeting, vol. 35, pp. 22-44, 2019.

. Mattia Bartoli, Luca Rosi, Marco Frediani, Unsaturated Polyester Resins Fundamentals, Design, Fabrication, and Applications 2019, pp. 579-598.

. I. Khan, K. Saeed, “Nanoparticles: Properties, applications and toxicities”, Arabian Journal of Chemistry, vol. 12, pp. 908-931, 2017.

. Characteristics of Particles – Particle Size Categories. https://www.azonano.com/article.aspx.[ August 17, 2017].

. S. W. Ali, S. Rajendran and M. Joshi, “Synthesis and characterization of chitosan and silver loaded chitosan nanoparticles for bioactive polyester”, Carbohyd. Polym, vol. 83, pp. 438–446, 2011.

. Chengzhu Liao, Yuchao Li, Sie Chin Tjong, “Antibacterial Activities of Aliphatic Polyester Nanocomposites with Silver Nanoparticle sand/or Graphene Oxide Sheets”, Nanomaterials, vol. 9, pp. 1102, 2019.

. Pradip Kumar Dutta, Joydeep dutta and VS Tripathi, “Chitin and chitosan: chemistry, properties and applications”, Journal of Scientific and Industrial Research, vol. 63, pp. 20-31, 2004.

. S.-Y. Ong, J. Wu, S. M. Moochhala, M. H. Tan and J. Lu, “Development of a chitosan based wound dressing with improved hemostatic and antimicrobial properties”, Biomaterials, vol. 29, pp. 4323-4332, 2008.

. KC Song, SM Lee, TS Park, “Preparation of colloidal silver nanoparticles by chemical reduction method”, Korean Journal of Chemical Engineering, vol. 26, pp. 153-155, 2009.

. KS Chou, YC Lu, HH Lee, “Effect of alkaline ion on the mechanism and kinetics of chemical reduction of silver”, Mater Chem Phys. Vol. 94, pp. 429-433, 2005.

. Marya Raji et al., “Prediction of the cyclic durability of woven-hybrid composites”, Woodhead Publishing Series in Composites Science and Engineering, vol. 3, pp. 27-62, 2019.

. Stokes, J. Debbie, “Principles and Practice of Variable Pressure Environmental Scanning Electron Microscopy” (VP-ESEM). Chichester: John Wiley & Sons (2008).

. Joseph I. Goldstein, “Scanning Electron Microscopy and X-Ray Microanalysis”, Springer (2003).

. M. Puchalski et at., “The study of silver nanoparticles by scanning electron microscopy, energy dispersive X-ray analysis and scanning tunnelling microscopy”, Materials Science-Poland, vol. 25, pp. 473-478, 2007.

. Muhammed L. Sanyang, Salit M. Sapuan, Mohammad Jawaid, Mohamad R. Ishak, Japar Sahari, “Effect of Plasticizer Type and Concentration on Tensile, Thermal and Barrier Properties of Biodegradable Films Based on Sugar Palm (Arenga pinnata) Starch”, Polymers, vol. 7, pp. 1106-1124, 2015.

. B. Muthu Chozha Rajan, B. Senthil Kumar, V. Madhan, P. Paul Pandian, “Experimental Investigation and Analysis of Mechanical Properties of Palm Fiber Reinforced Epoxy Composites and Sisal Fiber Reinforced Polyester Composites”, Carbon-Science and Technology, vol. 7, pp. 1-15, 2015.

. MS Nurul and M Mariatti, “Effect of thermal conductive fillers on the properties of polypropylene composites”, Journal of Thermoplastic Composite Materials, vol. 26, pp. 627-639, 2011.

. F.W. Billmeyer, Text Book of Polymer Science (3rd edition), A Willey Interscience (1984).

. Michael F Ashby, Materials selection in mechanical design (Fourth edition), Elsevier (2011).

. Fatemeh Karchoubi, Reza Afshar Ghotli, Hossein Pahlevani, Mahsa Baghban Salehi, “New insights into nanocomposite hydrogels; a review on recent advances in characteristics and applications”, Advanced Industrial and Engineering Polymer Research, vol. 7, pp. 54-78, 2024.

. Howard Kuhn, Dana Medlin, Mechanical Testing and Evaluation, ASM Handbook (2000).

. Fatemeh Dolatzadeh, Siamak Moradian, Mohammad Mehdi Jalili, “Influence of various surface treated silica nanoparticles on the electrochemical properties of SiO2/polyurethane nanocoatings”, Corrosion Science, vol. 53, pp. 4248-4257, 2011.

. An Jing, Luo Qingzhi, Yuan Xiaoyan, Wang Desong, Li Xueyan, “Preparation and characterization of silver–chitosan nanocomposite particles with antimicrobial activity”, J Appl Polym Sci, vol. 120, pp. 3180-3189, 2011.

. P. Gupta, M. Bajpai, SK. Bajpai, “Investigation of antibacterial properties of silver nanoparticle-loaded poly (acrylamide-coitaconic acid)-grafted cotton fabric”, J Cotton Sci, vol. 12, pp. 280-286, 2008.

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Published

2024-09-05

How to Cite

Md. Ashadul Islam, Md. Waresh Hossain, Sajib Madbar, & Md. Asadul Hoque. (2024). Mechanical and Antibacterial Properties of Polyester/Chitosan/Ag Nanocomposite. International Journal of Sciences: Basic and Applied Research (IJSBAR), 73(1), 459–471. Retrieved from https://gssrr.org/index.php/JournalOfBasicAndApplied/article/view/16988

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