# Preamble and Applicability of a New Relation for the Estimation of Viscosity of Liquid Mixtures

## Keywords:

Chemical industry, Molecular interaction, Multicomponent system, Rheochor, Transport property## Abstract

A New relation for the estimation of viscosity of binary and ternary liquid mixtures has been proposed and tested for its validity. The results obtained from the newly proposed relation have been compared with the experimental values. For comparison, the relation based upon Flory Statistical Theory has also been utilized. Very good agreement between the experimental values and values obtained from the newly proposed relation vouch the applicability of the proposed relation for the estimation of viscosity of liquid mixtures.

## References

H. Eyring and J.O. Hirschfelder. “The theory of the liquid state”. J Phys Chem, vol. 41, pp. 249-257, 1939.

M.L. Williams, R. F. Landel and J.D. Ferry. “The temperature dependence of relaxation mechanisms in amorphous polymers and other glass-forming liquids”. J Chem Soc, vol. 77, pp. 3701-3707, 1955.

S. Glasstone, K.J. Laidler and H. Eyring. The Theory of Rate Processes. New York: McGrawHill, 1941.

P.J. Flory. “Statistical thermodynamics of liquid mixtures”. J Am Chem Soc, vol. 87, pp. 1833-1838, 1965.

P.J. Flory, R. A. Orwoll and A. Vrij. “Thermodynamics of chain molecule liquids an equation of state for normal paraffin hydrocarbons”. J Am Chem Soc, vol. 86, pp. 3507-3514, 1964.

H. Eyring, T. Ree and H. Hirai. “Significant structures in the liquid state”. Proc Nat Acad Sci USA, vol. 44, pp. 683-691, 1958.

H. Eyring and M.K. John. Significant liquid structures, New York: Wiley, 1969.

V.A. Bloomfield and K.K. Dewan. “Viscosity of liquid mixtures”. J Phys Chem, vol. 75, pp. 3113-3119, 1971.

J.T. Schrodt, and K.M. Arkel. “Binary liquid viscosities and their estimation from classical solution thermodynamics”. J Chem Eng Data, vol. 34, pp. 8-13, 1989.

L. Grunberg and A. H. Nissan. “Mixture law for viscosity”. Nature, vol. 164, pp. 799-800, 1949.

J. Kendall and K.P. Munroe. “The viscosity of liquids - the viscosity-composition curve for ideal liquid mixtures”. J Am Chem Soc, vol. 39, pp. 1787-1802, 1917.

E.C. Bingham. Fluidity and Plasticity. New York: McGrawHill, 1992.

R.A. McAllister. “Viscosity of liquid mixtures”. AIChE J, vol. 6, pp. 427, 1960.

J.D. Pandey and U. Gupta. “Theoretical evaluation of viscosity of binary molten electrolytes”. Electrochim Acta, vol. 29(3), pp. 403-405, 1984.

I.L. Acevedo and M. Kartz. “Viscosities and thermodynamics of viscous flow of some binary mixtures at different temperatures”. J Soln Chem, vol. 10(19), pp. 1041-1052, 1990.

J.D. Pandey, P. Jain and V. Vyas. “Speed of sound, viscosity, and refractive index of multicomponent systems: analysis of experimental data from the Bertrand–Acree–Burchfield equation”. J Soln Chem, vol. 72, pp. 2486-2492, 1994.

Z. Shan and A.A. Asfour. “Viscosities and densities of eight binary 1-alkanol systems at 308.15 and 313.15 K”. Fluid Phase Equilibria, vol. 143, pp. 253-262, 1998.

T. M. Aminabhavi and K. Banerjee. “Thermodynamic interactions in binary mixtures of 1-chloronaphthalene with n-alkanes”. Ind J Chem, vol. 40A, pp. 53-64, 2001.

J.D. Pandey, S. Pandey, S. Gupta and A.K. Shukla. “Viscosity of ternary liquid mixtures”. J Soln Chem, vol. 23(9), pp. 1049-1059, 1994.

J.D. Pandey, A. K. Shukla, V.K. Sanguri and S. Pandey. “Viscosities of quaternary liquid solutions”. J Soln Chem, vol. 24, pp. 1191-1196, 1995.

A. Kumagai and C. Yokoyama. “Viscosity of aqueous solutions of CO2 at high pressures”. Intl J Thermophysics, vol. 19, pp. 1315-1323, 1998.

B.D. Bhatt. “Comparative study on the empirical methods and group contribution method for the evaluation of the viscosities of liquid mixtures”. Int J Chem Studies, vol. 6(5), pp. 1965-1968, 2018.

B. D. Bhatt. “Applicability of the statistical mechanical theory for the estimation of viscosity in the organic liquid mixtures”. Int J Chem Sci, vol. 2(3), pp. 36-40, 2018.

J.D. Pandey, R. Dey and B.D. Bhatt. “Application of Flory’s statistical theory for the estimation of internal pressure of the liquid mixtures”. J Chem Research, vol. S, pp. 430-432, 2003.

## Downloads

## Published

## How to Cite

*International Journal of Sciences: Basic and Applied Research (IJSBAR)*,

*56*(1), 410–418. Retrieved from https://gssrr.org/index.php/JournalOfBasicAndApplied/article/view/12439

## Issue

## Section

## License

Authors who submit papers with this journal agree to the following terms.